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Calcium Cored Wire in the Steel Metallurgy Industry

In the steel metallurgy industry, Calcium Cored Wire is an indispensable tool to keep high speed in production and accurately control the elements in casting. It can also partly change the shape of inclusions in molten steel and improve the quality of the steel.

During ladle refining, the powder additive package is injected into the steel at a specific depth with the help of professional core wire machines. The powder weight shows the amount of core sheath and filling powder per coil.

Calcium monosilicide (CaSi)

Calcium silicide is a material used to make pure cored wire for iron and steel production. It is added to molten steel for Deoxidation; Desulphurization and Inclusion Modification of the steel. It is injected in the steel ladle with help of wire injection system and achieve high yields of Ca in molten steel as compared to conventional method of adding CaSi lumps at bottom of the ladle.

The solubility of calcium in liquid steel is very low at the steelmaking temperatures. Therefore, unless the ferrostatic head is very high, Ca can only enter the steel in a gaseous state. This is the reason why cored wires are used to ensure contact between Ca and liquid steel.

The quality of the cored wire depends on the ratio of solid core to molten steel, the quality of the powder core and the feeding position. Ideally, the feed point should be at the center of the molten steel flow and stay away from the argon blowing circle. This will enable the calcium to enter the molten steel in a liquid state and extend its residence time in the molten steel.

Calcium silicate (CaSi)

Adding calcium metal to the steel melt during steelmaking helps prevent clogging of caster nozzles. It also globularises the inclusions and improves the transverse properties of the steel. It also acts as a deoxidizer and reduces the chemical composition of other metallic inclusions.

Cored wires have been used in the industry for a long time now and they have helped in maintaining high speed production, controlling accuracy of the chemical elements in casting and reducing the cost of the process. Several types of cored wire are available on the market now, which include calcium silicon cored wire, chromium aluminium alloy cored wire, nodularization cored wires and inoculation cored wires.

Cored wires are usually delivered in vertical coils on wooden (or steel) pallets, plastic shrink wrapped and labeled. The metallurgists use these coils to determine the correct feed depth for the metal they need to add to the molten steel. The specific filling weight shows the powder amount in g/m of the coil.

Calcium aluminate (CaAl)

Calcium aluminate (CaAl) is a refractory material which can be used as core for wire addition in steel metallurgy. It is typically supplied in the form of pellets or briquettes for direct use in steelmaking processes, including deoxidization, desulfurization, and spheroidization of cast iron.

The key to maximizing the efficiency of this method of addition is determining an appropriate feeding position for the cored wire. This should be at the center of the molten steel flow and away from the argon blowing circle, where it will have the most contact with the liquid steel.

This allows the cored wire to penetrate deeper into the steel melt, thereby reducing deformation of the calcium strips and increasing the speed at which they can be absorbed by the steel. It can also help to improve the quality of the steel, reduce alloy consumption, and shorten smelting time. The cored wire is also a cost-effective alternative to refractory bricks and other conventional methods of adding calcium.

Calcium sulfate (CaSiS)

The core of pure calcium cored wire consists of a metal sheath tightly wrapped around a powder additive package, which can be varied depending on the steel type and manufacturer. This allows the alloy to be injected into the steel ladle in a manner that makes contact between the Ca vapour and liquid steel as intimate as possible.

Using specialized equipment, the alloy is inserted smoothly into the molten steel and melts in the proper position to produce a chemical reaction. This eliminates the need to put in the powder directly into molten steel, which can cause combustion and generate calcium bubbles that can damage the furnace. It also avoids the reaction of added elements with air and slag, increases element yield, and improves the quality of the steelmaking and casting products. This is also a safe way to add deoxidizers, desulfurization agents and alloying materials to the molten steel. It can be used as a pretreatment for trimming major components and microalloying.

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